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100% Power Frieza uses this power up while fighting Super Saiyan Goku on Namek, presumably at the beginning of the fight as he had the upper hand at that point, and later to further power himself up just before using his Nova Strike.
Appearances in games
Long awaited-for 100% was named and is used by 100% Power Frieza and Mecha Frieza in the Budokai Tenkaichi series and Dragon Ball: Raging Blast 2. This move puts Frieza into Sparking mode, puts his energy to max, and gives him a few other temporary bonuses.